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Motorola built what they called an all solid state B&W TV around 1960. This TV was called "The Astronaut" or something to that effect. I am not sure about the HV rectifier or how good a set this was. Philco also built what the called an all solid state B&W TV about this time. The Philco's are fairly collectable.
These are the earliest solid state TVs that I am aware of.
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