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DO NOT dump glacial acetic acid into a pool like that (if you happen across some). If the smell doesn't blow you away (it can damage the lungs) it will likely dissolve the pool. A half gallon of vinegar probably won't do much of anything, but hey, it can't hurt, and it's cheap enough.
I remember seeing a posting with pictures of this kiddie pool submersion method, and they stuck popsicle sticks into the edges of the pva as it worked loose. It did a great deal to speed up the process.
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