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I'm not familiar with the electron theory but negative on the electrolytic capacitors goes to ground; hooked up the other way they go poof.
Chances are you'll eventually tear up something, or at least do a sloppy job and want to re-do it eventually, I did quite a bit in the early stages of the learning process. By the way I always use 105 degree Nichicon capacitors. Avoid oddly-branded Chinese caps at all cost.
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